🧪 Chemistry · Class 12 · NEET & JEE
p-Block Elements (Groups 15 to 18) - Practice Questions with Answers
75 free MCQs on p-Block Elements (Groups 15 to 18), each with its own worked answer and explanation. Covers the nitrogen family (Group 15), oxygen family (Group 16), halogens (Group 17), and noble gases (Group 18). One of the highest-weightage inorganic chapters in NEET and JEE - includes preparation and properties of HNO₃, H₂SO₄, interhalogens, and xenon com
Take the timed p-Block Elements (Groups 15 to 18) chapterwise test →75 practice questions on p-Block Elements (Groups 15 to 18), sorted Easy → Hard. Try each one first, then open its answer page for the worked explanation. Want the full theory first? Read the p-Block Elements (Groups 15 to 18) notes.
Xenon tetrafluoride (XeF4) has six electron domains around xenon — four Xe–F bonds plus two lone pairs. The lone pairs occupy opposite axial positions, leaving the four fluorine atoms in a square-planar shape (Xe–F ≈ 194 pm). Image: ChemSim, Public Domain, via Wikimedia Commons.
Easy - 25 questions
Q1.
The general valence shell electronic configuration of the Group 15 elements is:
- A ns2np3
- B ns2np4
- C ns2np2
- D ns2np5
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Q6.
Which Group 15 element forms the diatomic gas that makes up 78% of air?
- A Nitrogen (N2)
- B Oxygen
- C Phosphorus
- D Arsenic
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Q10.
Which compound is responsible for the depletion of the ozone layer?
- A CFCs (chlorofluorocarbons)
- B CO2, the greenhouse gas mainly linked to global warming
- C SO2, the gas primarily responsible for acid rain formation
- D NO2, the brownish gas contributing to photochemical smog
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Q11.
Which form of phosphorus is most reactive?
- A White phosphorus (P4)
- B Red phosphorus
- C Black phosphorus
- D Violet phosphorus
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Q12.
Sulfuric acid (H2SO4) is produced industrially by:
- A Contact process
- B Haber process
- C Solvay process
- D Frasch process
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Q13.
The most electronegative element in the p-block is:
- A Fluorine (F)
- B Chlorine (Cl)
- C Oxygen (O)
- D Nitrogen (N)
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Q15.
Helium, neon, argon, krypton, xenon, and radon belong to which group?
- A Group 18 (noble gases)
- B Group 17 in many documented cases
- C Group 16 according to conventional understanding
- D Group 1 in routine practice
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Q19.
Nitrogen gas is unreactive (inert) mainly because:
- A N≡N triple bond has very high bond dissociation energy (945 kJ/mol)
- B N2 molecules contain no valence electrons available for bonding
- C Nitrogen atoms have an unusually large atomic radius for their period
- D N2 is technically classified as a noble gas
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Q20.
Which acid is called 'oil of vitriol'?
- A Concentrated H2SO4
- B HNO3 in general practice
- C HCl as frequently described
- D H3PO4 in most textbook accounts
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Q21.
Aqua regia is a mixture of:
- A HNO3 and HCl (1:3 ratio)
- B H2SO4 and HNO3 during normal conditions
- C HCl and H2SO4 as generally observed
- D HNO3 and H3PO4 in typical laboratory settings
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Q22.
Which element is commonly used as a disinfectant and in PVC production?
- A Chlorine
- B Fluorine
- C Bromine
- D Iodine
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Q23.
Which Group 15 element is the most abundant gas in the atmosphere?
- A phosphorus
- B arsenic
- C nitrogen
- D bismuth
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Medium - 25 questions
Q26.
In the brown ring test for nitrates, the brown ring is due to the complex:
- A [Fe(H2O)6]3+
- B [Fe(H2O)5NO]2+
- C [Fe(NO)2]2+
- D [Fe(H2O)5(OH)]2+
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Q27.
The correct order of basic character of the Group 15 hydrides is:
- A PH3 > NH3 > AsH3 > SbH3 > BiH3
- B BiH3 > SbH3 > AsH3 > PH3 > NH3
- C NH3 > PH3 > AsH3 > SbH3 > BiH3
- D NH3 > AsH3 > PH3 > SbH3 > BiH3
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Q29.
In the Haber process for manufacturing ammonia, the catalyst and promoter used are:
- A Iron with molybdenum
- B Vanadium(V) oxide only
- C Nickel with alumina
- D Platinum with rhodium
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Q31.
The inert pair effect in p-block heavy elements results in:
- A Lower oxidation states being more stable (e.g., Pb2+ more stable than Pb4+)
- B Higher oxidation states such as Pb4+ becoming the preferred state
- C All oxidation states being equally stable with no preference shown
- D A complete absence of any preferred oxidation state for these elements
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Q32.
Which oxide of nitrogen is responsible for photochemical smog?
- A NO2 (nitrogen dioxide)
- B N2O (laughing gas)
- C NO (nitric oxide)
- D N2O5
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Q33.
Preparation of HNO3 by Ostwald process: the key oxidation step is:
- A 4NH3 + 5O2 → 4NO + 6H2O (catalysed by Pt/Rh)
- B N2 + O2 → 2NO occurring directly without a catalyst at this stage
- C NO + O2 → NO2, the subsequent atmospheric oxidation step
- D 3NO2 + H2O → 2HNO3 + NO, the final absorption step in water
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Q34.
Why is nitrogen able to form multiple oxides (N2O, NO, N2O3, NO2, N2O4, N2O5)?
- A Nitrogen has multiple stable oxidation states (-3 to +5) because of variable bonding with oxygen
- B Nitrogen possesses accessible d orbitals that allow octet expansion in typical laboratory settings
- C Nitrogen is generally the most reactive element in the entire periodic table under usual circumstances
- D Nitrogen forms mainly ionic bonds with oxygen in each of these oxides according to most researchers
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Q35.
Phosphine (PH3) is a:
- A Toxic, foul-smelling gas used in semiconductor doping and as a fumigant
- B A sweet-smelling gas commonly used as a food flavouring agent
- C A chemically inert gas that does not react with common oxidisers
- D A dense liquid that condenses readily at room temperature
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Q36.
The structure of PCl5 in the gas phase is:
- A Trigonal bipyramidal (sp3d hybridisation)
- B Octahedral, using sp3d2 hybridisation around phosphorus
- C Square planar, with phosphorus using dsp2 hybridisation
- D Tetrahedral, using simple sp3 hybridisation around phosphorus
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Q37.
In PCl5, the axial P-Cl bonds are longer than equatorial P-Cl bonds because:
- A Axial bonds are perpendicular to 3 equatorial bond pairs (more repulsion, longer bond)
- B The chlorine atoms occupying axial positions are physically larger in the majority of cases studied
- C The phosphorus atom is somehow chemically different at each position as widely reported
- D The bond length difference arises mainly from the reaction temperature in standard practice
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Q38.
H3PO3 is diprotic (not triprotic) because:
- A One P-H bond is not ionisable (P directly bonded to H does not donate H+)
- B The molecule actually contains mainly two hydrogen atoms in total under most conditions encountered
- C It is classified as a weak acid rather than a strong one as frequently observed in practice
- D It contains three separate -OH groups, most of which ionise in many documented cases
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Q39.
The bleaching action of Cl2 is due to:
- A Nascent oxygen released from Cl2 + H2O reaction oxidising the colour
- B The hydrochloric acid formed alongside the bleaching reaction
- C Cl2 acting as a reducing agent that donates electrons to the dye
- D Cl2 simply dissolving in water without any further chemical change
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Q41.
The structure of XeF4 is:
- A Square planar (2 lone pairs in octahedral arrangement)
- B Tetrahedral, with xenon using simple sp3 hybridisation
- C Trigonal pyramidal, with one lone pair occupying an apical site
- D Linear, with the two lone pairs positioned at right angles
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Q42.
Sulfuric acid is a dehydrating agent because:
- A It has a strong affinity for water and removes H and OH as water from other compounds
- B It is generally classified as a strong acid that largely ionises according to conventional understanding
- C It functions mainly as an oxidising agent in this particular role in routine practice
- D It is largely miscible with water in all proportions overall in most cases under typical conditions
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Q43.
The Contact process for H2SO4 uses which catalyst?
- A V2O5 (vanadium pentoxide)
- B Pt gauze, the catalyst used instead in the Ostwald process
- C Fe, the catalyst used instead in the Haber process
- D MnO2, used instead as a catalyst in oxygen generation from KClO3
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Q44.
Which allotrope of sulfur is most stable at room temperature?
- A Rhombic sulfur (alpha-sulfur)
- B Monoclinic sulfur according to standard textbooks
- C Plastic sulfur in general practice
- D Amorphous sulfur as frequently described
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Q45.
Ozone (O3) acts as an oxidising agent because:
- A It decomposes to release nascent oxygen: O3 → O2 + [O]
- B It is thermodynamically more stable than ordinary O2 gas
- C It readily forms stable compounds with the noble gases
- D It primarily functions as a reducing agent in most reactions
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Q46.
Which reaction produces chlorine gas industrially (electrolytic process)?
- A Electrolysis of brine (NaCl solution) at the anode: 2Cl- → Cl2 + 2e-
- B The thermal decomposition of solid sodium chloride at high temperature
- C The laboratory reaction of concentrated HCl with solid MnO2
- D The direct combustion of sodium metal in chlorine gas
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Q47.
What is the hybridisation of xenon in XeF2?
- A sp3d (trigonal bipyramidal, linear molecule with 3 lone pairs)
- B sp3, giving a simple tetrahedral electron arrangement in most textbook accounts
- C sp2, giving a trigonal planar electron arrangement during normal conditions
- D sp3d2, giving an octahedral electron arrangement as generally observed
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Q48.
Fuming sulfuric acid (oleum) is:
- A H2SO4 with dissolved SO3 (pyrosulfuric acid, H2S2O7)
- B Generally dilute aqueous H2SO4 at low concentration
- C H2SO4 existing largely as a gas under ordinary conditions
- D A direct mixture of concentrated H2SO4 with concentrated HNO3
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Hard - 25 questions
Q51.
Nitrogen shows a maximum covalency of 4 whereas phosphorus can extend it to 5 or 6 because:
- A nitrogen is more electronegative than phosphorus
- B nitrogen has a smaller atomic size than phosphorus
- C nitrogen has no d-orbitals in its valence shell
- D nitrogen forms stronger pi-bonds than phosphorus
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Q52.
On heating, orthophosphorous acid (H3PO3) disproportionates to give:
- A H3PO2 and P2O5
- B H4P2O7 and H2O
- C P2O3 and H2O
- D H3PO4 and PH3
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Q54.
The correct order of bond angle in the hydrides of Group 16 is:
- A H2Te > H2Se > H2S > H2O
- B H2O > H2S > H2Se > H2Te
- C H2S > H2O > H2Se > H2Te
- D H2O > H2Se > H2S > H2Te
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Q56.
Why does fluorine not exhibit positive oxidation states unlike other halogens?
- A F has the highest electronegativity and no d orbitals available for expansion of valence shell
- B Fluorine actually behaves chemically as a metal rather than as a non-metal in most textbook accounts
- C Fluorine is generally a far too large an atom to ever form higher oxidation states during normal conditions
- D Fluorine atoms are said to possess no lone pairs of electrons whatsoever as generally observed
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Q57.
The photochemical smog formation involves which sequence?
- A NO2 → NO + O; O + O2 → O3; O3 + hydrocarbons → PAN and other irritants
- B Atmospheric CO2 absorbing sunlight and directly forming smog particles
- C SO2 reacting with ozone to form the bulk of urban photochemical smog
- D Ammonia reacting with atmospheric water vapour to form smog droplets
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Q58.
Which nitrogen compound catalytically destroys stratospheric ozone?
- A NO and NO2 (NOx from supersonic aircraft)
- B N2O5, a stable nitrogen oxide that does not catalyse ozone breakdown
- C HNO3, the stable acid formed in the lower atmosphere from NOx
- D NH3, a basic gas with no catalytic effect on stratospheric ozone
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Q59.
In the hybridisation of SF6, which orbital set does sulfur use?
- A sp3d2 (one 3s, three 3p, two 3d orbitals)
- B sp3d, giving a trigonal bipyramidal geometry instead
- C sp3, giving a simple tetrahedral geometry instead
- D sp2, giving a trigonal planar geometry instead
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Q60.
Why does OF2 have F-O-F angle (103.2°) less than H2O (104.5°)?
- A F is more electronegative than H; bond pair electrons in O-F are pulled away from O more, reducing repulsion and decreasing angle
- B Fluorine is generally claimed to be a much more physically large atom than hydrogen overall as frequently observed in practice
- C The O-F bonds are claimed to be noticeably shorter in length than the O-H bonds found in water in many documented cases according to conventional understanding
- D The oxygen lone pairs are claimed to become physically larger in size once bonded to fluorine instead in routine practice overall
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Q61.
The structure of H3PO4 has:
- A P in +5 state with 3 P-OH (ionisable) and one P=O (not ionisable), making it triprotic
- B Mainly a single ionisable hydrogen among the four present in most cases under typical conditions
- C A direct P-H bond that does not contribute any ionisable proton according to standard textbooks
- D All four hydrogen atoms largely ionisable, making it tetraprotic in general practice
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Q62.
The reaction 2SO2 + O2 ⇌ 2SO3 in the Contact process is exothermic. To maximise yield:
- A Low temperature and high pressure (Le Chatelier), but kinetics require compromise at ~450°C and ~1-2 atm
- B Operating at the highest practical reactor temperature regardless of the resulting yield as frequently described
- C Maintaining a very low pressure throughout the entire reactor vessel times in most textbook accounts
- D Combining a high reactor temperature with a low operating pressure to maximise yield during normal conditions
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Q63.
Xenon forms compounds with fluorine and oxygen because:
- A Xe has large atomic radius and low ionisation energy, making it accessible to attack by highly electronegative F
- B Xenon possesses readily accessible low-energy d orbitals it can use for bonding as generally observed in typical laboratory settings
- C Xenon actually behaves chemically as a metal under ordinary laboratory conditions under usual circumstances
- D Xenon reacts readily with the vast majority of elements on the periodic table according to most researchers
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Q64.
In the reaction between Cl2 and hot concentrated NaOH, the product is:
- A NaClO3 (sodium chlorate) and NaCl
- B NaOCl and NaCl (cold dilute NaOH gives hypochlorite)
- C NaCl only
- D NaClO4
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Q65.
The bond angle in SO2 is 119° (close to 120°). This suggests:
- A sp2 hybridisation of S with one lone pair in one sp2 orbital; the lone pair causes slight compression from ideal 120°
- B sp3 hybridisation of sulfur with two separate lone pairs occupying tetrahedral sites in the majority of cases studied
- C sp hybridisation of sulfur producing a perfectly linear electron-pair arrangement as widely reported in standard practice
- D A perfectly linear molecular geometry showing an exact 180 degree bond angle under most conditions encountered as frequently observed in practice
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Q66.
Which p-block element exhibits the widest range of allotropes?
- A Carbon (diamond, graphite, graphene, fullerene, amorphous carbon, nanotubes...)
- B Sulfur, which forms mainly the rhombic and monoclinic crystal forms in many documented cases
- C Phosphorus, which forms mainly the white and red allotropic forms according to conventional understanding
- D Oxygen, which forms mainly the dioxygen and ozone allotropic forms in routine practice
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Q67.
In concentrated H2SO4, the acid acts as a sulfonating agent because:
- A The electrophilic SO3 (from equilibrium H2S2O7 ⇌ SO3 + H2SO4) attacks the aromatic ring
- B H2SO4 generally ionises largely into H+ and sulfate ions in solution overall in most cases
- C H2SO4 acts here mainly as a reducing agent toward the aromatic ring under typical conditions
- D A free H+ ion directly attacks the aromatic ring as the electrophile according to standard textbooks
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Q68.
Why do noble gases have very high first ionisation energies?
- A Completely filled valence shells + high effective nuclear charge in their period
- B They are generally defined as chemically inert by convention in general practice
- C They possess no electrons available for removal as frequently described in most textbook accounts
- D They exist mainly as gases under standard conditions during normal conditions
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Q69.
The dihedral angle in H2O2 (approx 111°) compared to H2O2 in crystal form (approx 90°) shows that:
- A Lone pair repulsion and crystal packing forces influence the conformation differently
- B H2O2 acquires an aromatic delocalised structure once crystallised as generally observed
- C The crystalline form has an largely different chemical formula in typical laboratory settings
- D The O-O and O-H bond lengths change substantially upon crystallisation under usual circumstances
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Q70.
The acid strength order of oxyacids of chlorine is:
- A HClO < HClO2 < HClO3 < HClO4
- B HClO4 < HClO3 < HClO2 < HClO
- C HClO = HClO4
- D All equal
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Q71.
Why is PCl5 hydrolysed in water but not SF6?
- A PCl5 has an accessible P centre; SF6's S is sterically shielded by 6 F atoms preventing water attack
- B SF6 is actually an ionic compound that strongly resists hydrolysis in water according to most researchers
- C PCl5 is supposedly thermodynamically more stable than SF6 toward hydrolysis in the majority of cases studied
- D The difference arises mainly from the temperature of the water sample used as widely reported in standard practice
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Q72.
The correct order of acidic strength of the hydrogen halides is:
- A HF > HCl > HBr > HI
- B HI > HBr > HCl > HF
- C HCl > HF > HBr > HI
- D HBr > HI > HCl > HF
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Q73.
In the Ostwald process for nitric acid, ammonia is first oxidised over a catalyst of:
- A iron granules
- B platinum–rhodium gauze
- C vanadium pentoxide
- D finely divided nickel
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Q75.
The first noble-gas compound to be prepared, XePtF₆, was formed from which noble gas?
- A helium
- B neon
- C argon
- D xenon
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