🧪 Chemistry · Class 11 · NEET & JEE
Redox Reactions - Practice Questions with Answers 75 free MCQs on Redox Reactions, each with its own worked answer and explanation. Master electron transfer in chemistry: assign oxidation states, balance half-reactions, identify oxidising and reducing agents, and connect redox to everyday reactions.
Take the timed Redox Reactions chapterwise test → 75 practice questions on Redox Reactions , sorted Easy → Hard. Try each one first, then open its answer page for the worked explanation. Want the full theory first? Read the Redox Reactions notes .
Electron Transfer: Zn + Cu²⁺ → Zn²⁺ + Cu Zn loses 2e⁻ OXIDISED (Zn → Zn²⁺) 2e⁻ Cu²⁺ gains 2e⁻ REDUCED (Cu²⁺ → Cu) Zn = reducing agent Cu²⁺ = oxidising agent Electron transfer in a redox reaction: zinc loses electrons (oxidised, acts as reducing agent) and copper(II) ions gain those same electrons (reduced, acts as oxidising agent).
Easy - 25 questions Q2.
In a redox reaction, oxidation involves:
A Gain of electronsB Gain of protonsC No net changeD Loss of electronsShow answer & explanation →
Q10.
In the reaction 2Mg + O2 → 2MgO, magnesium is:
A ReducedB OxidisedC Acting as an oxidising agentD UnchangedShow answer & explanation →
Q11.
An oxidising agent:
A Donates electrons and gets oxidisedB Accepts electrons and gets reducedC Does not change its oxidation stateD Only works in acidic conditionsShow answer & explanation →
Q14.
In the reaction Zn + CuSO4 → ZnSO4 + Cu, zinc is:
A ReducedB Neither oxidised nor reducedC OxidisedD Acting as an oxidising agentShow answer & explanation →
Q16.
Which of the following is a common oxidising agent?
A H2 gas under typical conditionsB C (carbon) according to standard textbooksC KMnO4 (potassium permanganate)D Na (sodium metal) in general practiceShow answer & explanation →
Q18.
Rusting of iron is an example of:
A Reduction of ironB Oxidation of ironC NeutralisationD Decomposition without redoxShow answer & explanation →
Q19.
In a redox reaction, the substance that gets oxidised is called the:
A Oxidising agentB Reducing agentC AcidD ElectrolyteShow answer & explanation →
Q21.
In the electrolytic decomposition of water: 2H2 O → 2H2 + O2 , oxygen is:
A OxidisedB ReducedC Not involved in the redoxD Acting as a reducing agentShow answer & explanation →
Q23.
A disproportionation reaction is one in which:
A Two largely different elements undergo a simultaneous oxidation-reduction exchangeB The same element is simultaneously oxidised and reducedC Mainly a single reduction half-reaction occurs without any oxidationD Mainly a single oxidation half-reaction occurs without any reductionShow answer & explanation →
Q24.
In the reaction 2H2 O2 → 2H2 O + O2 , H2 O2 undergoes:
A Mainly oxidation, since every oxygen atom ends up in O2 B Mainly reduction, since every oxygen atom ends up in H2 OC Both oxidation and reduction (disproportionation)D Neither oxidation nor reduction, since the reaction is mainly physicalShow answer & explanation →
Q25.
Which of the following processes is an example of reduction?
A Magnesium burning in oxygen to form magnesium oxideB Iron slowly forming rust in the presence of moist airC Copper(II) oxide reacting with hydrogen to form copperD Sodium metal reacting vigorously with water to release hydrogen gasShow answer & explanation →
Medium - 25 questions Q33.
In the reaction: Cr2 O7 2- + Fe2+ → Cr3+ + Fe3+ (acidic), how many Fe2+ ions are oxidised per one Cr2 O7 2- ion?
Show answer & explanation →
Q35.
When Cu reacts with dilute H2 SO4 , no reaction occurs. But with concentrated H2 SO4 , the reaction gives:
A CuSO4 + H2 B CuSO4 + SO2 + H2 OC Cu2 SO4 + H2 D CuO + H2 SShow answer & explanation →
Q37.
Balance the redox reaction in basic medium: MnO4 - + I- → MnO2 + I2 . The balanced equation is:
A 2MnO4 - + I- → 2MnO2 + IO3 - in most textbook accountsB 2MnO4 - + 3I- + H2 O → 2MnO2 + 1.5I2 + 2OH- during normal conditionsC 2MnO4 - + 3I- + 2H2 O → 2MnO2 + I2 + 4OH-... (check)D MnO4 - + 2I- → MnO2 + I2 as generally observedShow answer & explanation →
Q39.
What is the oxidation state of iron in Fe3 O4 ?
A All iron present as Fe2+ throughout the entire compoundB All iron present as Fe3+ throughout the entire compoundC Mixed: 1/3 Fe2+ and 2/3 Fe3+ (average +8/3)D All iron present as the unusually high Fe4+ oxidation stateShow answer & explanation →
Q40.
The reaction Cl2 + 2NaOH → NaCl + NaOCl + H2 O is an example of:
A Simple oxidationB Disproportionation of Cl2 C ElectrolysisD Acid-base neutralisation onlyShow answer & explanation →
Q41.
Which of the following can act as both an oxidising agent and a reducing agent?
A KMnO4 B F2 C H2 O2 D K2 Cr2 O7 Show answer & explanation →
Q43.
In the ion-electron method of balancing, when balancing the following half-reaction in acidic medium: Cr2 O7 2- → Cr3+ , how many electrons are transferred?
Show answer & explanation →
Q44.
In the reaction: 2F2 + 2H2 O → 4HF + O2 , fluorine is:
A Oxidised from -1 to 0B Reduced from 0 to -1C Acting as reducing agentD Undergoing disproportionationShow answer & explanation →
Q45.
What is the change in oxidation state of sulphur when H2 S is converted to SO2 ?
A -2 to +2 (change of +4)B 0 to +4 (change of +4)C -2 to +4 (change of +6)D +2 to +4 (change of +2)Show answer & explanation →
Q47.
In the reaction: Zn + 2HCl → ZnCl2 + H2 , identify the oxidising agent:
A Zn, the metal that is itself oxidised in this reactionB H2 , the gas that is itself the reduction product hereC HCl (specifically H+)D Cl-, the spectator ion that does not change oxidation stateShow answer & explanation →
Q49.
Bleaching powder decolourises coloured substances because:
A It acts as a reducing agent that adds hydrogen to the dye's chromophoreB The Ca(OCl)Cl releases nascent oxygen which oxidises the colouring matterC It simply dissolves the dye molecules away into the surrounding solutionD It is mildly basic and chemically neutralises the acidic dye structureShow answer & explanation →
Q50.
The method of balancing redox reactions that involves calculating the change in oxidation numbers and multiplying coefficients to make total increase = total decrease is called:
A Ion-electron methodB Half-reaction methodC Oxidation number methodD Le Chatelier methodShow answer & explanation →
Hard - 25 questions Q51.
In the balanced acidic-medium reaction MnO4 − + Fe2+ + H+ → Mn2+ + Fe3+ + H2 O, the mole ratio of MnO4 − to Fe2+ is:
A 1 : 5B 1 : 3C 1 : 6D 1 : 2Show answer & explanation →
Q55.
For a spontaneous redox reaction, the standard cell potential E°cell and ΔG° must be, respectively:
A Positive and positiveB Negative and negativeC Positive and negativeD Negative and positiveShow answer & explanation →
Q56.
Balance the following redox reaction in acidic medium: MnO4 - + C2 O4 2- → Mn2+ + CO2 . What are the stoichiometric coefficients (MnO4 - : C2 O4 2- )?
A 1 : 1B 2 : 5C 5 : 2D 3 : 5Show answer & explanation →
Q58.
What is the oxidation state of sulphur in peroxomonosulphuric acid (Caro acid, H2 SO5 )?
A +6 (one S-OH and one S-O-O-H group making it a peroxoacid)B +4, the oxidation state characteristic of sulfur in SO2 insteadC +8, an oxidation state not actually accessible to sulfur in any compoundD +2, an unusually low oxidation state not seen in this peroxoacidShow answer & explanation →
Q60.
The comproportionation reaction (reverse of disproportionation) has the general form: A(higher OS) + A(lower OS) → A(intermediate OS). Which of the following is an example?
A 2H2 O2 → 2H2 O + O2 B Cu2+ + Cu → 2Cu+C Cl2 + 2NaOH → NaCl + NaOCl + H2 OD 2MnO4 - + 5H2 C2 O4 → 2Mn2+ + 10CO2 + 8H2 OShow answer & explanation →
Q61.
In the permanganate titration of ferrous ions in acidic medium, the end point is determined by:
A The pale yellow-brown colour of the Fe3+ product appearing suddenly at the endpointB Persistent pale pink colour of excess KMnO4 (self-indicator)C Addition of a starch indicator that turns blue-black at the endpointD A sharp change in the measured pH of the titration mixtureShow answer & explanation →
Q63.
Assign the oxidation state of each element in [Fe(CN)6 ]4- and determine the oxidation state of iron:
A Fe = +2 (CN- is -1 each; 6(-1) + Fe = -4; Fe = +2)B Fe = +3, the oxidation state found instead in the ferricyanide ionC Fe = 0, the oxidation state found instead in neutral iron carbonylsD Fe = +4, an oxidation state not consistent with this complex's overall chargeShow answer & explanation →
Q64.
Balance the redox reaction in basic medium: Cr3+ + H2 O2 → CrO4 2- + H2 O. What is the oxidising agent?
A Cr3+ , the species that is itself oxidised to chromate in this reactionB H2 O2 (H2 O2 oxidises Cr3+ to CrO4 2- )C H2 O, the product formed and therefore not the oxidising agentD OH-, the basic medium ion that does not change oxidation stateShow answer & explanation →
Q65.
The equivalent weight of K2 Cr2 O7 in acidic medium (where Cr goes from +6 to +3) is:
A Molar mass / 3B Molar mass / 6C Molar mass / 1D Molar mass / 2Show answer & explanation →
Q66.
In the reaction of F2 with water: F2 + H2 O → HF + HOF, fluorine:
A Undergoes disproportionation (one F atom is 0→-1 and the other is 0→+1 in HOF)B Is mainly reduced, with both fluorine atoms ending at the -1 oxidation stateC Is mainly oxidised, with both fluorine atoms ending at a positive oxidation stateD Does not change oxidation state throughout the reaction in typical laboratory settingsShow answer & explanation →
Q67.
In calculating n-factor for Na2 S2 O3 in its reaction with I2 (where products include Na2 S4 O6 ), the n-factor of Na2 S2 O3 is:
Show answer & explanation →
Q68.
What happens to the oxidising power of KMnO4 as the pH of the medium decreases (more acidic)?
A DecreasesB Remains unchangedC IncreasesD Becomes zeroShow answer & explanation →
Q70.
During iodometric back-titration, Na2 S2 O3 is used to titrate liberated I2 . The reaction is: 2S2 O3 2- + I2 → S4 O6 2- + 2I-. What is the role of Na2 S2 O3 here?
A Oxidising agentB Reducing agentC Both oxidising and reducing agentD CatalystShow answer & explanation →
Q71.
The reaction: 5H2 O2 + 2KMnO4 + 3H2 SO4 → 2MnSO4 + K2 SO4 + 5O2 + 8H2 O shows that H2 O2 is acting as:
A Oxidising agent (Mn7+ → Mn2+ , so KMnO4 is reduced by H2 O2 )B Reducing agent (H2 O2 is oxidised: O from -1 to 0 in O2 )C CatalystD Neither oxidised nor reducedShow answer & explanation →
Q72.
In the reaction: 3Cl2 + 6NaOH (hot and conc.) → 5NaCl + NaClO3 + 3H2 O, which of the following statements is correct?
A Cl is mainly reduced, with every chlorine atom ending up as chloride ionB Cl disproportionates: 0 → -1 (in NaCl) and 0 → +5 (in NaClO3 )C Cl is mainly oxidised, with every chlorine atom ending up in NaClO3 D NaOH itself acts as the reducing agent that is consumed in this reactionShow answer & explanation →
Q73.
A sample of iron ore weighing 1.00 g is dissolved in acid and all iron converted to Fe2+ . The solution requires 25.0 mL of 0.0200 M KMnO4 for titration. The percentage of Fe in the ore is approximately:
A 14.0%B 7.0%C 28.0%D 5.6%Show answer & explanation →
Q74.
In photo-oxidation of silver halides during photography, the reaction Ag+ + e- → Ag involves:
A Oxidation of Ag+ to a higher silver oxidation state by absorbed lightB Reduction of Ag+ to Ag0 by light-generated electronsC Disproportionation of silver into two different oxidation states simultaneouslyD Direct oxidation of the silver ion by the halide ions presentShow answer & explanation →
Q75.
Using the standard electrode potentials E°(Fe3+ /Fe2+ ) = +0.77 V and E°(I2 /I-) = +0.54 V, predict whether Fe3+ will oxidise I- ions:
A No, generally because E°(Fe3+ /Fe2+ ) is said to be less than E°(I2 /I-) under these conditionsB Yes, because E°(Fe3+ /Fe2+ ) > E°(I2 /I-) so the cell EMF is positive and the reaction is spontaneousC No reaction occurs, since both given half-reaction potentials are positive values in routine practiceD Both species are said to function mainly as oxidising agents and so cannot react together overallShow answer & explanation →