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🧪 Chemistry  ·  Surface Chemistry  ·  NEET & JEE

A colloidal sol of As2S3 is negatively charged. Which combination correctly ranks the coagulating power of NaCl, MgCl2, and AlCl3 from least to most effective, based on the Hardy-Schulze rule?

Answer: NaCl less than MgCl2 less than AlCl3.

  • A AlCl3 less than MgCl2 less than NaCl
  • B NaCl less than MgCl2 less than AlCl3
  • C MgCl2 less than NaCl less than AlCl3
  • D All three are equally effective regardless of cation charge

Correct answer: B. NaCl less than MgCl2 less than AlCl3

Explanation: Coagulating power increases with the valency of the oppositely charged ion. Since the sol is negative, cations matter: Na+ (1+) is weakest, Mg2+ (2+) is intermediate, and Al3+ (3+) is the strongest coagulant.

Adsorption Isotherm: x/m vs PressureP (pressure)x/mlow P: x/m ∝ Phigh P: saturation plateauAt high pressure, all surface sites are occupied - the curve flattens (monolayer saturation)

A typical adsorption isotherm: x/m (mass adsorbed per gram of adsorbent) rises steeply at low pressure, then flattens into a saturation plateau as the adsorbent surface fills up.

Concept context

Explore the chemistry that happens at interfaces, from catalysts that speed up industrial reactions to colloids like milk, smoke, and gels that surround us every day.

Read the full Surface Chemistry notes →